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CSEC>> Chemistry

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More revision questions
Francine Taylor-Campbell, Contributor

We will examine some more questions as part of your examination preparations.

Question 1

1. The following results were obtained by burning methane and using the energy obtained to heat a known mass of water:

Mass of water = 250g
Initial temperature of water = 26°C
Final temperature of water = 36°C
Mass of methane = 0.2g

Use this information to calculate the heat of combustion in KJ per mole of methane. Assume that there are no heat losses and that the 4.2J of energy are needed to raise the temperature of 1g of water by 1°C.

ANSWERS

Q1. Heat change for rxn = mass of soln x heat capacity of soln x temperature change. This is an equation worth remembering!

DH = 250g x 4.2 Jg-1C-1 x 10 C = 10.5 KJ

This energy change was given out from the burning of 0.2g of methane.

1 mole of methane (CH4) has a mass of (12 + 4) = 16g

# mol in 0.2g = 0.2/16 = 0.0125 mol

Thus 0.0125 mol give out 10.5 KJ of heat

1 mole = 10.5/0.0125 = 840 KJ/mol

Now attempt this question.

Question 2

2. Give the equation for the reaction between methane and steam.

Calculate the maximum volume of hydrogen, measured at s.t.p., which can be obtained from 16g of methane.

Answers

(a) CH4 (g) + H2O (g) ? CO (g) + 3H2 (g)

(b) Mr of CH4 = 12+ (1*4) = 16

#mol CH4 = 16/16 = 1 mol

Based on reaction, 1 mol of CH4 produces 3 mol of H2 gas

At s.t.p, 1 mol of any gas = 22.4 dm-3

Volume of 3 mol H2 = 3*22.4 = 67.2 dm-3

To ensure that you are properly preparing for your exams, try practising past-paper questions under exam conditions. That is, try answering the questions in the time normally set for the exams. In this way you get used to working fast and with a time limit.

Good luck in your exams and continue to study hard!

Carolyn Supersad (left), promotions manager for PediaSure at Cari-Med, greets students at the Covenant Christian Academy and Children's Centre (from second left) Khori Bennett, Ashli Findlator and Robyn-Leigh Hearne. PediaSure is the official drink of the Covenant/Globe Over-Distance Track Meet, now in its 10th year. They were at the launch of the meet on April 14 at Globe Insurance Company in New Kingston.
- Contributed

Francine Taylor-Campbell is an independent contributor.


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