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CSEC>> Chemistry

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Past-paper questions (5)
Francine Taylor-Campbell, Contributor

1. Two of the isotopes of phosphorous are 32P, which is radioactive, and 31P, which is not radioactive.

(a) Explain the meaning of isotopes and of radioactive in this statement.

(ii) How many electrons, protons and neutrons are present in one atom of 32P?

(iii) Give one use of a named radioactive isotope.

(b) An element is in Group VI of the Periodic Table. Give two chemical properties which this element is likely to have.

(c) Name one of the elements in Group O of the Periodic Table. Give a use for this element.

ANSWERS

1a. Isotopes are elements having the same atomic number (protons) but different mass number (neutrons). A substance is said to be radioactive if its nucleus is unstable and readily breaks down to give smaller atoms and emits radiation.

(ii) 32P has 15 protons and 15 electrons. # neutrons = 32 - 15 = 16

(iii) 14C is used in determining the age of rocks

(b) An element in Group VI would be an oxidising agent and would form covalent compounds with non-metals.

(c) Helium is in Group O which is also known as Group 8. It is used to fill weather balloons.

2. This question is based on the following oxides; carbon dioxide, copper II oxide, sodium oxide, carbon monoxide, silicon dioxide and sulphur dioxide.

(a)Which oxide has a macromolecular structure?

(b)Which oxide is used to bleach wood pulp in the manufacture of paper?

(a) Which oxides are acidic and which are basic?

(b) Which oxides are common atmospheric pollutants?

(c) Which oxide is the main constituent of sand?

(d) Which oxide produces a blue solution when heated with dilute sulphuric acid?

ANSWERS

2. (a) Silicon dioxide

(b) Sulphur dioxide

(c) Carbon dioxide, silicon dioxide and suphur dioxide are acidic while copper II oxide and sodium oxide are basic.

(d) Carbon monoxide and sulphur dioxide

(e) Silicon dioxide

(f) Copper II oxide ( CuO + H2SO4 = CuSO4 blue + H2O)

3. Explain the following terms. In each case, give a specific example to illustrate your answer. In your answers, use formulae or symbols as appropriate.

(a) Relative molecular mass, Mr

(b) Allotropes of an element

(c) Cracking

(d) Corrosion

(e) Electrolysis

(f) Anhydrous salts

(g) Saturated solution

(h) Hard water

(i) Hydrocarbon

ANSWERS

3. (a) Relative molecular mass refers to the ratio of the mass of the molecule to 1/12 the mass of carbon-12. The Mr of CO = 12 + 16 = 28

(b) Allotropes are forms of the same element having different structural formulae but existing in the same state. They possess the same chemical properties but different physical properties. For example, Diamond (C) and graphite (C)

(c) Cracking is the process of breaking up large hydrocarbon molecules into smaller ones. For example, C9H20 ==== C4H8 + C5H12 Nonane breaks up to give butene and pentane.

(d) Corrosion is the eating away of a solid surface (metal) by the action of air, moisture and pollutants. For example, iron corrodes to form rust which is hydrated iron III oxide (Fe2O3.xH2O)

(e) Electrolysis refers to the decomposition of a substance by the passing of electric current through it. For example, molten NaCl gives Na and Cl2 when electrolysed.

(f) Anhydrous salts are those that have lost their water of crystallisation. Eg CuSO4 (white) from CuSO4.5H2O (blue)

(g) Saturated solution is one which contains as much solute as can be dissolved in it at a given temperature.

(h) Hard water refers to water that does not lather easily with soap due to dissolved calcium and magnesium salts. CaSO4, MgSO4, Ca(HCO3)2 and Mg(HCO3)2

(i) Hydrocarbon is a substance containing only carbon and hydrogen. For example, CH4 is a hydrocarbon.

Francine Taylor-Campbell is an independent contributor. Send questions and comments to kerry-ann.hepburn@gleanerjm.com

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